Reaction path search for the asymmetric hydrogenation catalyzed by rhodium(III) monohydride complex

 

Authors：Haruki Nagae

Affiliation：Graduate School of Engineering Science, Osaka University

Abstract：当研究室でこれまでに開発してきた3つの塩素によって架橋されたRh(III)モノヒドリド錯体による不斉水素化反応について、新たに単離した単核錯体をモデルとして、錯体の立体の評価および反応経路探索を行った。

 

Publication related to your research
（Journal paper）

  • Kosuke Higashida, Fabian Brüning, Nagataka Tsujimoto, Kenya Higashihara, Haruki Nagae, Antonio Togni, and Kazushi Mashima ” Monohydride-dichloro Rhodium(III) Complexes with Chiral Diphosphine Ligands as Catalysts for Asymmetric Hydrogenation of Olefinic Substrates”, Submitted.

 

（Etc）

  • Kosuke Higashida, Fabian Brüning, Nagataka Tsujimoto, Kenya Higashihara, Haruki Nagae, Antonio Togni, and Kazushi Mashima ” Monohydride-dichloro Rhodium(III) Complexes with Chiral Diphosphine Ligands as Catalysts for Asymmetric Hydrogenation of Olefinic Substrates”, Submitted.

 



Posted : March 01,2020